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Taking a Tailored Approach to Material Design: A Mechanistic Study of the Selective Localization of Phase-Separated Graphene Microdomains
RETURN TO ARTICLES ASAPPREVFunctional Nanostruc...Functional Nanostructured Materials (including low-D carbon)NEXT Suihua He Bristol Composites Institute, School of Civil, Aerospace, and Design Engineering, Queen’s Building, University of Bristol, University Walk, Bristol BS8 1TR, U.K. , Baris Demir Centre for Theoretical and Computational Molecular Science, The Australian Institute for Bioengineering and Nanotechnology, The University of Queensland, Brisbane, Queensland 4072, Australia ,...
Solvent‐derived Fluorinated Secondary Interphase for Reversible Zn‐graphite Dual‐ion Batteries
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
Solvent‐derived Fluorinated Secondary Interphase for Reversible Zn‐graphite Dual‐ion Batteries
Abstract The irreversibility of anion intercalation-deintercalation is a fundamental issue in determining the cycling stability of a dual-ion battery (DIB). In this work, we demonstrate that using a partially fluorinated carbonate solvent can drive a beneficial fluorinated secondary interphase layer formation. Such layer facilitates reversible anion (de-)intercalation processes by impeding solvent molecule co-intercalation and the associated graphite exfoliation.
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