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Photodissociation of Cr(CO)4bpy$$ \mathrm{Cr}{\left(\mathrm{CO}\right)}_4\mathrm{bpy} $$: A Non‐Adiabatic Dynamics Investigation
1 Introduction Metal complexes with a d 6 $$ {d}^6 $$ electron configuration exhibit rich excited state behavior through a combination of an electron-rich center, closely spaced d-orbitals, and a shell of stabilizing and electron-accepting ligands. One of their most intriguing properties is the ligand-selective photodissociation under UV light, for instance, of a carbonyl ligand [1].
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