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Bayler G. Barnes

As seen in: Nature, ACS Publications
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Articles

Multinuclear uranium-nitrogen cluster formation from exploration of organouranium-ammonolysis

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By Ved Prakash, Bayler G. Barnes, Cory J. Windorff
| Nature Verified
Abstract Uranium-nitrogen compounds (UxNy) pose interesting structural and electronic questions. Understanding the formation and speciation of UxNy may provide insights in nitrogen fixation as well as the preparation of potential uranium nitride nuclear fuels, a promising Gen IV nuclear reactor fuel. Small molecular clusters offer the opportunity to study UxNy using solution and dynamic spectroscopies.
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Synthesis, Characterization, and Light Sensitivity in Titanium Piano Stool Alkyl and Sulfur Complexes, [(C5Me5)TiMe2R]n− (R = Me, SCPh3, S; n = 0, 1)

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By Alejandro Metta-Magaña, Eric W. Reinheimer, Cory J. Windorff, Bayler G. Barnes
| ACS Publications
Introduction Click to copy section linkSection link copied! The field of organotitanium chemistry has been dominated by biscyclopentadienyl compounds of the general form (C5R5)2TiX2-n(L/Z)n, for combinations of anionic (X), neutral (L) or Z-type ligands. (C5R5)2TiX2-n(L/Z)n complexes are used in a variety of applications including olefin polymerization, catalysis for fine chemicals, reductive coupling, dinitrogen activation, photocatalysis, and more.
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