Benjamin Groff on Muck Rack

Benjamin Groff

Los Angeles
As seen in: Medium, ACS Publications
Executive VP, Creative Kobalt Music Group. Former guitar shredder.
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Articles

Disentangling Driving Force Effects, Polar Effects, e–/H+ Imbalance, and Other Influences on H-Atom Transfer Reactions

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By Benjamin Groff, Mauricio Cattaneo, Brandon Mercado, Katheryn C. Rinaolo
| ACS Publications
Journal of the American Chemical Society Cite this: J. Am. Chem. Soc. 2025, XXXX, XXX Click to copy citationCitation copied! Learn about these metrics Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days. Citations are the number of other articles citing this article, calculated by Crossref and updated daily.
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Polar Effects in Hydrogen Atom Transfer Reactions from a Proton-Coupled Electron Transfer (PCET) Perspective: Abstractions from Toluenes

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By Benjamin Groff, Brian Koronkiewicz, Lubom Ar
| dx.doi.org
Hydrogen atom transfer (HAT) has been one of the fundamental reactions of organic chemistry for over a century (eq 1). It is common in biological transformations, atmospheric chemistry, combustion, catalysis, and synthetic chemistry. In catalysis and synthesis, achieving the required selectivity is often difficult.
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Independent Tuning of the pKa or the E1/2 in a Family of Ruthenium Pyridine-Imidazole Complexes

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By Benjamin Groff, Mauricio Cattaneo, Scott C. Coste, Chloe A. Pressley
| dx.doi.org
Two series of RuII(acac)2(py-imH) complexes have been prepared, one with changes to the acac ligands and the other with substitutions to the imidazole. The proton-coupled electron transfer (PCET) thermochemistry of the complexes has been studied in acetonitrile, revealing that the acac substitutions almost exclusively affect the redox potentials of the complex (|ΔE1/2| ≫ |ΔpKa|·0.059 V) while the changes to the imidazole primarily affect its acidity (|Δpa|·0.059 V ≫ |Δ1/2|).
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