Is this you? As a journalist, you can create a free Muck Rack account to customize your profile, list your contact preferences, and upload a portfolio of your best work.
Claim your profile
Articles by Bertold Rasche
Synthetic Access to Alkali Metal Selenides via Ball Milling
1 Introduction Alkali metal selenides are of particular interest as precursors for a variety of selenium compounds. Sodium monoselenide (Na2Se), for example, is a powerful reagent used to introduce selenium in a manifold of organoselenium compounds [1-3]. The strong nucleophilic nature of sodium selenide is utilised to form heterocycles or dialkylselenides [4, 5]. Na2Se crystallises in the antifluorite structure type [6] as colourless crystals.
Discovering Perovskite-Derived Tungsten Bronzes from In Situ Diffraction of Electrochemical Rubidium and Cesium Intercalation
Introduction Click to copy section linkSection link copied! Electrochemistry provides an unmatched possibility to shift chemical equilibria and, therefore, transform solid structures at a constant temperature. Combining this powerful tool with in situ diffraction enables direct observation of structural transitions, allowing to resolve structural intermediates or new (meta-)stable phases.
Front Cover: The Divalent Lanthanoid Triflates Ln(CF3SO3)2(CH3CN) (Ln=Sm, Eu): Structure, Luminescence, and Magnetism (Chem. Eur. J. 24/2024)
Request Username Can't sign in? Forgot your username? Enter your email address below and we will send you your username If the address matches an existing account you will receive an email with instructions to retrieve your username
The Divalent Lanthanoid Triflates Ln(CF3SO3)2(CH3CN) (Ln=Sm, Eu): Structure, Luminescence, and Magnetism
Introduction The chemistry of the lanthanoids is strongly stamped by the trivalent oxidation state and by the fact that the f-electrons of these elements are strongly shielded and are essentially not involved in chemical bonding.1-4 On the other hand, the well-shielded electrons lead to unique physical properties of the Ln3+-ions, and especially their luminescence and their magnetism have attracted significant attention that has led to various applications.5-9 The luminescence of most...
Alkaline Metal Intercalates of VSe2 by Electrochemical Intercalation
Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
Acoustic cavitation generates molecular mercury(II) hydroxide, Hg(OH)2, from biphasic water/mercury mixtures
This article is Open Access Please wait while we load your content... Something went wrong. Try again?
Acoustic Cavitation Generates Molecular Mercury (II) Hydroxide, Hg(OH)2, from Biphasic Water/Mercury Mixtures
This article is Open Access Please wait while we load your content... Something went wrong. Try again?
In‐situ electrochemical X‐ray diffraction: A rigorous method to navigate within phase diagrams reveals β‐Fe1+xSe as superconductor for all x - Rasche - - Angewandte Chemie International Edition - Wiley Online Library
Communication In‐situ electrochemical X‐ray diffraction: A rigorous method to navigate within phase diagrams reveals β‐Fe1+xSe as superconductor for all x Richard G.
A metallic room-temperature oxide ion conductor
Nanoparticles of Bi3Ir, obtained from a microwave-assisted polyol process, activate molecular oxygen from air at room temperature and reversibly intercalate it as oxide ions. The closely related structures of Bi3Ir and Bi3IrOx (x≤2) were investigated by X-ray diffraction, electron microscopy, and quantum-chemical modeling. In the topochemically formed metallic suboxide, the intermetallic building units are fully preserved.
Show More
loading
Actions
Is this you?
As a journalist, you can create a free Muck Rack account to customize your profile, list your contact preferences, and upload a portfolio of your best work.Get in touch with Bertold
Contact Bertold, search articles and posts on X, monitor coverage, and track replies from one place.
Learn more about Muck Rack