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Niko T Flosbach

As seen in: Wiley Online Library, Royal Society of Chemistry
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Articles

Subzero-Temperature NMR Observation of Protein Dynamics and Ligand Binding Enabled by Encapsulation Within Coordination Cages

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By Kevin Sheehy, Lorraine M Bateman, Niko T Flosbach
| Wiley Online Library Verified
1 Introduction Nuclear magnetic resonance (NMR) spectroscopy has proven to be a powerful tool for investigating protein dynamics, yet motions occurring faster than the NMR timescale remain challenging to characterize [1-3]. In addition to relaxation-dispersion analyses [4, 5] and advanced pulse-sequence methodologies [6-8], lowering the temperature represents an attractive means of analyzing rapid dynamics by slowing them down enough to be observable [9-24].
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High Pressure Synthesis of Pr2O5 - A Unique Lanthanoid(IV) Oxide Peroxide

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By Niko T Flosbach, Lukas Brüning, Pascal L. Jurzick, Elena Bykova
| Wiley Online Library Verified
The unique physical and chemical properties of the lanthanoids make them essential components in modern technologies, including electronics, optical devices, and magnetic materials.1 The chemistry of the lanthanoids is dominated by the +III oxidation state that is the most stable for all elements of the series. However, variations in the electronic configuration of lanthanoids in different oxidation states significantly influence the physical properties of their ions.
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Front Cover: The Divalent Lanthanoid Triflates Ln(CF3SO3)2(CH3CN) (Ln=Sm, Eu): Structure, Luminescence, and Magnetism (Chem. Eur. J. 24/2024)

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By Niko T Flosbach, Bertold Rasche, Leonhard Rochels, Sabrina Disch
| Wiley Online Library Verified
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