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Bis(Vinylenedithio)‐Tetrathiafulvalene‐Based Coordination Networks
Graphical Abstract Sulphurous lateral interactions. For electroactive coordination polymers, through space charge transport phenomenon are most often 1D. By increasing the size of the electroactive core, lateral sulphur-sulphur interaction take place and create a 2D conducting pathway. Post-synthetic oxidation is used to increase the materials conductivity. Abstract Novel coordination polymers embedding electroactive moieties present a high interest in the development of porous conducting materials.
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