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Cambell S. Conour

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Articles

Plutonium(III) versus uranium(III) and samarium(III) in small molecule activation chemistry

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By Megan Keener, Thayalan Rajeshkumar, Joshua Woods, Laurent Maron, Polly L. Arnold, Cambell S. Conour
| Nature Verified
Abstract We report the PuIII complex, [PuIII(CpMe4)3] (1-Pu), and demonstrate its differences in small molecule reactivity compared to the UIII and SmIII analogs, [UIII(CpMe4)3] (1-U) and [SmIII(CpMe4)3] (1-Sm), respectively. 1-Pu reductively cleaves the small molecule (PhS)2, affording a PuIII complex, [{PuIII(CpMe4)2}2(μ-SPh)2] (2-Pu), while retaining the PuIII center and eliminating (CpMe4)2 as a by-product, a fingerprint of a sterically induced reduction (SIR) reaction.
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