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Guest-controlled polymorphism and exceptionally marked bi-stability in a spin crossover 3D porous amino-functionalized coordination polymer
Guest-controlled polymorphism and exceptionally marked bi-stability in a spin crossover 3D porous amino-functionalized coordination polymer Functionalization of spin crossover (SCO) porous coordination polymers (PCPs) with hydrogen-bonding active groups is an efficient strategy for the research of multifunctional materials. Indeed, the interaction of guests with the host framework may improve the cooperativity of the SCO inducing eventual occurrence of bi-stability.
Broad-range spin-crossover modulation in guest-responsive 2D Hofmann-type coordination polymers
Broad-range spin-crossover modulation in guest-responsive 2D Hofmann-type coordination polymers† Alejandro Orellana-Silla,‡a Rubén Turo-Cortés, ‡a Víctor Rubio-Giménez, b Carlos Bartual-Murgui, *a Rob Ameloot, b Carlos Martí-Gastaldo, a M.
Broad-range spin-crossover modulation in guest-responsive 2D Hofmann-type coordination polymers
Broad-range spin-crossover modulation in guest-responsive 2D Hofmann-type coordination polymers Alejandro Orellana-Silla, Rubén Turo-Cortés, Víctor Rubio-Giménez, Carlos Bartual-Murgui, Rob Ameloot, Carlos Martí-Gastaldo, M. Carmen Muñoz and José Antonio A Real Cabezos Abstract Rationalizing the role of chemical functionalisation on the synergy between spin crossover (SCO) and guest adsorption properties in porous FeII coordination polymers is a central topic within the switchable materials area.
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