Cecilia Anderson

REMO Self-Assembly Pathways Figure 5 compares the 31 P NMR spectrum of the A 1-mer and the UV–vis absorption spectrum of the D 1-mer with corresponding spectra of the AOnD oligomers. The 31 P NMR signals in the oligomer spectra are broadened, and in some cases, splitting is apparent, which is due to population of different rotamers around the exocyclic nitrogen triazine bond that are in slow exchange on the chemical shift time scale.

Introduction Click to copy section linkSection link copied! Developments in directed evolution have enabled scientists to efficiently sample biochemical sequence space, allowing the discovery of new functional molecules in a time- and resource-effective manner. (1,2) However, this process relies on the transfer of information encoded by DNA or RNA sequences and limits the structures that can be explored to nucleic acids and peptides.

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