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A Microfluidic Gradient Generator Post-Modified by Two-Photon Direct Laser Writing for Dynamic Particle Functionalization
1 Introduction Microfluidics emerges as a powerful tool to integrate multiple laboratory steps into a single device and to control fluids on a microscale [1, 2]. This is especially useful in lab-on-a-chip (LOC) devices for chemical synthesis, biochemical reactions, cell culturing, or biomedical sciences [3-5].
Palladium‐Catalyzed Cyclization of a Pyryne Precursor to Higher Pyrenylenes
Graphical Abstract By palladium-catalyzed oligomerization reactions of pyrene-based o-trimethylsilyl triflates larger cyclic pyrenylenes were formed with up to 10-membered rings as has been unambiguously characterized by SCXRD. Furthermore, the underlying reaction mechanism has been studied by quantum chemical calculations.
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