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The Strategies of Improving Chemical Stability of Imine-Linked Covalent Organic Frameworks
Conflicts of Interest The authors declare no conflicts of interest. Data Availability Statement Data sharing is not applicable to this article as no datasets were generated or analyzed during the current study. References 1, , , et al., “Molecular Docking Sites Designed for the Generation of Highly Crystalline Covalent Organic Frameworks,” Nature Chemistry 8 (2016): 310–316, https://doi.org/10.1038/nchem.2444.
Amide synthesis via transaminative amidation of aromatic aldehydes/ketones: An entry to 15N isotopologs
Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description adsc202401592-s1-SI_1.doc5.8 MB Supplementary adsc202401592-s2-SI_2.pdf12.9 MB Supplementary
Rh(III)-catalyzed selective C2 C–H acyloxylation of indoles
Rh(iii)-catalyzed selective C2 C–H acyloxylation of indoles† Herein, we present the first highly regio- and chemoselective C2 C–H acyloxylation of indole under rhodium catalysis and an N-quinolinyl auxiliary. This strategy accommodates a wide range of indoles and structurally diverse carboxylic acids with good reaction efficiencies to yield functionalized indoles. The utility of this logic was demonstrated by the concise synthesis of the functionalized 2-oxindole derivatives.
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