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As a journalist, you can create a free Muck Rack account to customize your profile, list your contact preferences, and upload a portfolio of your best work.Articles
Integrating Authentic Research, Peer Learning, and High-Impact Project Work into the General Chemistry Laboratory
Chelsea A. Barr [1] ; Drew R. Brodeur [1] ; Uma Kumar [1] ; Destin W. Heilman [1] [1] Worcester Polytechnic Institute, United States Localización: Journal of chemical education, ISSN 0021-9584, Vol. 99, Nº 12, 2022, págs. 3899-3905 Idioma: inglés Texto completo no disponible (Saber más ...) For the past several decades, high-enrollment undergraduate chemistry laboratory experiences have favored traditional approaches involving disparate daily experiments with optimized protocols provided to students.
Zinc Photocages with Improved Photophysical Properties and Cell Permeability Imparted by Ternary Complex Formation
Photocaged complexes can control the availability of metal ions to interrogate cellular signaling pathways. We describe a new photocage, {bis[(2-pyridyl)methyl]amino}(9-oxo-2-xanthenyl)acetic acid (XDPAdeCage, 1), which utilizes a 2-xanthone acetic acid group to mediate a photodecarboxylation reaction. XDPAdeCage photolyzes with a quantum yield of 27%, and binds Zn2+ with 4.6 pM affinity, which decreases by over 4 orders of magnitude after photolysis.
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