Chongtao Li on Muck Rack

Chongtao Li

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Articles

Stereoselective photometallobiocatalytic cross-coupling of organoboron reagents and diazo compounds via an outer-sphere mechanism

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By Huanan Wang, Binh Khanh Mai, Xiao-Wang Chen, Rachel Weiss Verified, Bryan J. Kudisch, Peng Liu, Chongtao Li
| Nature Verified
Abstract Designing and developing synthetically useful biocatalytic reactions that operate through unconventional mechanisms represent a central challenge in modern biocatalysis research. By coupling photoredox catalysis and metalloenzyme catalysis, here we harness cooperative photometallobiocatalysis to merge enzymatically generated, open-shell iron carbenoids with reactive radical intermediates formed via excited-state chemistry.
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