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Cancer remains a natural enemy of human life and health, which has been poorly treated by conventional cancer therapies such as surgery, radiotherapy and chemotherapy owing to side effects, metastasis and drug resistance [1]. Immunotherapy such as PD-1/PD-L1 checkpoint blockade, a promising anti-cancer strategy, is also severely limited by insufficient infiltration of immune cells in tumor microenvironment [2], [3], [4].
Cerium is a fascinating element due to its diverse physical properties, which include forming various crystal structures (γ, α, α′, α′′, and ε), mixed valence behavior, and superconductivity, making it an ideal platform for investigating the interplay between different electronic states.
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