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Liquid‐Phase Synthesis of Highly Reactive Rare‐Earth Metal Nanoparticles
Abstract The first liquid-phase synthesis of high-quality, small-sized rare-earth metal nanoparticles (1–3 nm)—ranging from lanthanum as one of the largest (187 pm) to scandium as the smallest (161 pm) rare-earth metal—is shown. Size, oxidation state, and reactivity of the nanoparticles are examined (e.g., electron microscopy, electron spectroscopy, X-ray absorption spectroscopy, selected reactions).
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