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Daniel Velev Latchev

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Articles

Plasmonic Hot‐Carrier Redox Enables Proton‐Coupled Electron Transfer at C─H Bonds

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By Julian Heeg, Jacinto Sa, Daniel Velev Latchev, Arthur Andreis
| Wiley Online Library Verified
Proton-coupled electron transfer (PCET) underlies many of nature's most demanding redox processes and has emerged as a central principle in synthetic catalysis, enabling the activation of strong and otherwise inert X─H bonds (X = N, O, C) under mild conditions.[1-3] By coupling electron and proton motion, PCET lowers activation barriers and avoids high-energy ionic intermediates, thereby imparting control and selectivity in transformations ranging from enzymatic reactions to photoredox...
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Plasmonic Hot‐Carrier Redox Enables Proton‐Coupled Electron Transfer at C─H Bonds

|
By Daniel Velev Latchev, Arthur Andreis, Julian Heeg, Jacinto Sa
| Wiley Online Library Verified
Proton-coupled electron transfer (PCET) underlies many of nature's most demanding redox processes and has emerged as a central principle in synthetic catalysis, enabling the activation of strong and otherwise inert X─H bonds (X = N, O, C) under mild conditions.[1-3] By coupling electron and proton motion, PCET lowers activation barriers and avoids high-energy ionic intermediates, thereby imparting control and selectivity in transformations ranging from enzymatic reactions to photoredox...
Open in Who Shared Issue with article?
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