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Aqueous/Nonaqueous DBU Mixtures: Versatile Switching Media for Chemoselective Aldol, Baylis‐Hillman, and Aldol Condensation Reactions
Introduction Organic reactions are inherently unselective due to usual presence of several active sites in the reactants with comparable enthalpies of activations.1 Additionally, prochirality and stereotopicity issues associated with the nature of specific functional groups give rise to the formation of enantiomeric and diastereomeric mixtures in many organic reactions, increasing the diversity of the products in synthetic operations.2 A recent promising, fast-growing solution to this...
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