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Pressure Scanning Volumetry of Physically Aged Polymer Glasses, Fictive Pressure, and Memory Effect
Physical aging of a glass decreases its volume, V, entropy, and enthalpy, H, toward the equilibrium state values. For glasses usually formed by cooling a melt, the effect is modeled in terms of non-exponential, nonlinear structural relaxation by using a plot of the heat capacity, Cp = (dH/dT)p, against T obtained from differential scanning calorimetry (DSC) cooling and heating scans.
Dielectric Characterization of Core-Shell Structured Poly(Vinylidene Fluoride)-Grafted-BaTiO3 Nanocomposites
This is an early access version, the complete PDF, HTML, and XML versions will be available soon.
Aging kinetics of levoglucosan orientational glass as a rate dispersion process and consequences for the heterogeneous dynamics view
Aging kinetics of a glass is currently modeled in terms of slowing of its α-relaxation dynamics, whose features are interpreted in terms of dynamic heterogeneity, i.e., formation and decay of spatially and temporally distinct nm-size regions.
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