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Putting Cyaphide in its Place: Determining the Donor/Acceptor Properties of the κC-Cyaphido Ligand Eric S Yang, Emma Combey and Jose M. Goicoechea Abstract The synthesis of group 9 pyridine-diimine complexes M(DippPDI)X and [M(DippPDI)L]+ (M = Co, Rh; DippPDI = 1,1’-(pyridine-2,6-diyl)bis(N-(2,6-diisopropylphenyl)ethan-1-imine; X = CP−, CCH−; L = CO, tBuNC) bearing a series of strong-field ligands, including the cyaphide ion (C≡P−), is reported.
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