Articles by Eric Schreiber
Reasoning Language Models: A Blueprint
Abstract Reasoning language models (RLMs), also known as Large Reasoning Models (LRMs), such as OpenAI's o1 and o3, DeepSeek-V3, and Alibaba's QwQ, have redefined AI's problem-solving capabilities by extending large language models (LLMs) with advanced reasoning mechanisms. Yet, their high costs, proprietary nature, and complex architectures - uniquely combining Reinforcement Learning (RL), search heuristics, and LLMs - present accessibility and scalability challenges.
Exfoliation of a Metal-Organic Framework Enabled by Post-Synthetic Cleavage of a Dipyridyl Dianthracene Ligand
Exfoliation of a Metal-Organic Framework Enabled by Post-Synthetic Cleavage of a Dipyridyl Dianthracene Ligand The synthetic tunability and porosity of two-dimensional (2D) metal-organic frameworks (MOFs) renders them a promising class of materials for ultrathin and nanoscale applications. Conductive 2D MOFs are of particular interest for applications in nanoelectronics, chemo-sensing, and memory storage.
O2 reduction via proton-coupled electron transfer by a V(III) aquo on a polyoxovanadate-alkoxide cluster
O2 reduction via proton-coupled electron transfer by a V(iii) aquo on a polyoxovanadate-alkoxide cluster† We report the transfer of H-atoms from a reduced polyoxovanadate alkoxide [nOct4N][V6O6(OH2)(OMe)12] via concerted proton–electron transfer. Oxygen reduction is compared between bridging and terminal O–H bonds revealing similar mechanisms, providing new insight to design criteria for metal-oxide electrocatalysts that faciliate oxygen reduction by concerted-proton electron transfer.
Heterometal Dopant Changes the Mechanism of Proton-Coupled Electron Transfer at the Polyoxovanadate-Alkoxide Surface
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2024, XXXX, XXX RETURN TO ARTICLES ASAPPREVCommunicationNEXT Shannon E. Cooney Department of Chemistry, University of Rochester, Rochester, New York 14627, United States , M. Rebecca A. Walls Department of Chemistry, University of Rochester, Rochester, New York 14627, United States , , , and * Cite this: J. Am. Chem. Soc. 2024, XXXX, XXX .
Heterometal Dopant Changes the Mechanism of Proton-Coupled Electron Transfer at the Polyoxovanadate-Alkoxide Surface
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2024, XXXX, XXX RETURN TO ARTICLES ASAPPREVCommunicationNEXT Shannon E. Cooney Department of Chemistry, University of Rochester, Rochester, New York 14627, United States , M. Rebecca A. Walls Department of Chemistry, University of Rochester, Rochester, New York 14627, United States , , , and * Cite this: J. Am. Chem. Soc. 2024, XXXX, XXX .
Uplevel security with Endpoint Privilege Management + Windows LAPS
by Charlize Cheesman Community Manager It's simple. Running devices as standard user can help lower your attack surface. Let's talk about the threats we face today, the keys to implementing "just enough" access for your users with Microsoft Intune Endpoint Privilege Management (EPM), and how to better secure local accounts with Windows LAPS. This session is part of the Microsoft Technical Takeoff: Windows + Intune.
Accelerated Rates of Proton Coupled Electron Transfer to Oxygen Deficient Polyoxovanadate-alkoxide Clusters
Accelerated Rates of Proton Coupled Electron Transfer to Oxygen Deficient Polyoxovanadate-alkoxide Clusters Shannon E Cooney, Eric Schreiber, William W. Brennessel and Ellen Matson Abstract Anionic dopants, such as O-atom vacancies, alter the thermochemical and kinetic parameters of proton-coupled electron transfer (PCET) at metal oxide surfaces; understanding the impact is essential for informed material design for efficient energy conversion processes.
Regioselectivity of Concerted Proton-Electron Transfer at the Surface of a Polyoxovanadate Cluster
Regioselectivity of Concerted Proton-Electron Transfer at the Surface of a Polyoxovanadate Cluster Eric Schreiber, William W. Brennessel and Ellen Matson Abstract Proton-coupled electron transfer (PCET) is an important process in the activation and reactivity of metal oxide surfaces. In this work, we study the electronic structure of a reduced polyoxovanadate-alkoxide cluster bearing a single bridging oxide moiety.
Surface Ligands Influence the Selectivity of Cation Uptake in Polyoxovanadate-alkoxide Clusters
Surface Ligands Influence the Selectivity of Cation Uptake in Polyoxovanadate-alkoxide Clusters Rachel E Garwick, Eric Schreiber, William W. Brennessel, James Robert McKone and Ellen Matson Abstract The selective uptake of lithium ions is of great interest for chemists and engineers because of the numerous uses of this element for energy storage and other applications.
Charge-State Dependence of Proton Uptake in Polyoxovanadate-alkoxide Clusters
Synopsis Experimental determination of the surface basicity of polyoxovanadate-alkoxide clusters across three oxidation states reveals a charge-state dependence of proton uptake in molecular, organofunctionalized vanadium oxide assemblies. Introduction The interactions of cations with the surface of reducible metal oxides (RMOs) is an important area of research, with implications in the advancement of energy storage technologies (1,2) and the development of catalysts.
Oxygen-Atom Defect Formation in Polyoxovanadate Clusters via Proton-Coupled Electron Transfer
Introduction Hydrogen atom (H-atom) uptake in reducible metal oxides has emerged as a popular route for doping materials with implications in catalysis, energy storage, and energy conversion. H-atom insertion has been accomplished through a number of methods, including hydrogen spillover (1−3) and the codoping of electrons and protons.
Modelling local structural and electronic consequences of proton and hydrogen-atom uptake in VO2 with polyoxovanadate clusters
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How to get motivated
Eric Schreiber Coastal Point • File photo Pro-level athletes are not more motivated than you are. Olympic athletes don’t just “want it more.” Every client of ours has the same struggles with motivation that you do. The difference? They know how to get motivated (and what to do when they don’t feel motivated at all). Ask anyone at the highest levels of fitness: Sometimes they don’t feel like working out (including your boy right here). And those folks with ripped abs?
Movement is Medicine: Tips for your resolution
It’s that time of year folks: the New Year is coming up! I think we all can’t wait for 2020 to be over — am I right!?!? Resolutions are always a big part of the New Year and getting healthy is a huge part of most people’s goals. “I want to get healthier this year.” “I’m going to lose 20, 30, 40 pounds in 2021.” “I’m going to eat healthier this year.” Sound familiar? Well, if any if this pertains to you, listen carefully! The health and wellness landscape has changed with COVID.
Movement is Medicine: The benefits of exercise and mental health
Exercise can help relieve stress. Coastal Point | Stock photo I’ve done videos and Facebook rants on this subject before, but I thought it might be time to put some hard facts and science on paper, to help educate my community on the importance of exercise and the role it plays on our mental health (which actually plays a large role in our immune system, i.e., stress).
Acid-Induced, Oxygen-Atom Defect Formation in Reduced Polyoxovanadate-Alkoxide Clusters
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2020, 142, 22 RETURN TO ISSUEPREVCommunicationNEXT Eric Schreiber Eric Schreiber Department of Chemistry, University of Rochester, Rochester, New York 14627, United States , Brittney E. Petel Brittney E. Petel Department of Chemistry, University of Rochester, Rochester, New York 14627, United States , and Ellen M.
Movement is Medicine: The carb conundrum
Carbs, carbs, carbs! Which ones do we eat? How much should we have? Will they make me gain weight? Carbohydrates have been the subject of great debate for the better half of a century, from the well-known Atkins, Zone and keto diets to even older and more obscure ones, such as the Air Force Diet and the Drinking Man’s Diet from the ’60s. Everywhere we look, there seems to be someone saying something different. So what do we do? Do we eat carbs or not?
Physicochemical implications of alkoxide "mixing" in polyoxovanadium clusters for nonaqueous energy storage
Physicochemical implications of alkoxide "mixing" in polyoxovanadium clusters for nonaqueous energy storage Identification of suitable charge carriers is essential for the success of nonaqueous energy storage systems. Thus, elucidation of structural parameters which affect the physicochemical properties of a molecule in organic solvent is of critical importance.
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