Friedrich-Alexander Universität Erlangen

The systematic review and NMA were performed in accordance with Preferred Reporting Items for Systematic Reviews and Meta-analysis (PRISMA) guidelines [12] and followed a pre-specified protocol. Selection criteria for the population, interventions, comparators, outcomes, and study design (PICOS) are outlined in Table 1.

Communication A Terminal Iron Nitrilimine Complex: Accessing the Terminal Nitride through Diazo N–N Bond Cleavage Karsten Meyer Corresponding Author E-mail address: karsten.meyer@fau.de Friedrich-Alexander Universität Erlangen - Nürnberg, Department Chemie und Pharmazie, Anorganische Chemie, Egerlandstr.

Reaction of the trivalent uranium complex [((Ad,MeArO)3N)­U(DME)] with one molar equivalent [Na(OCAs)(dioxane)3], in the presence of 2.2.2‐crypt, yields [Na(2.2.2‐crypt)]­[{((Ad,MeArO)3N)­UIV(THF)}­(μ‐O)­{((Ad,MeArO)3N)­UIV(CAs)}] (1), which is the arsenic containing analogue of the previously reported, μ‐oxo‐bridged di­uranium cyaphide complex. The structural characterization of complex 1 reveals the first example of a coordinated η1‐cyaarside ligand (CAs–).