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Cooperative Bimetallic Catalysis via One‐Metal/Two‐Ligands: Mechanistic Insights of Polyfluoroarylation‐Allylation of Diazo Compounds
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
Copper-catalyzed formylation of alkenyl C-H bonds with BrCHCl2 used as a stoichiometric formylating reagent
The first example of copper-catalyzed direct formylation of alkenyl C-H bonds for facile synthesis of ?,?-unsaturated aldehydes has been developed. This transformation has demonstrated high reactivity, mild reaction conditions and broad substrate scope. BrCHCl2 is expected to be developed as an effcient stoichimetric C1 bulding block in organic synthesis.
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