Giovanni Barcaro
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Photocatalyzed oxidative cleavage of alkenes using CO 2 as an oxygen donor
Editor’s summary Structured Abstract Abstract Supplementary Materials References and Notes Information & Authors Metrics & Citations Check Access References Figures Tables Media Share Editor’s summary Slicing through carbon-carbon double bonds is a job for strong oxidants. Typical reagents include ozone and high-valent metal oxides. Carbon dioxide is essentially the thermodynamic opposite of those oxidants and conventionally reacts at the carbon rather than either oxygen. Remarkably, Qin et al.
Electronic Transport in Porous Nanocrystals Enables Ultrasensitive Consistent Detection of Sulfur Dioxide under Variable Humidity Click to copy article link Article link copied!
2.1. MOF Synthesis and Characterization We synthesized DC-103 from a novel octahydroxy-functionalized TPz linker with a central cobalt ion, CoTPz(OH) 8 , coordinated to copper bridging ions through bis(dioxolene) linkages by following a similar approach to our previous report, (55) as detailed in Figures S1–S12 and Section S2 .
Redox-Active Metal–Organic Framework Nanocrystals for the Simultaneous Adsorption, Detection, and Detoxification of Heavy Metal Cations
1. Introduction Click to copy section linkSection link copied! The widespread contamination of water sources by heavy metal pollutants, driven by the extensive exploitation of natural resources, intensified human activities, and rapid industrialization processes, poses a significant threat to global health.
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