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Giovanni Barcaro on Muck Rack

Giovanni Barcaro

As seen in: Nature, Wiley Online Library, ACS Publications, Science Magazine, Royal Society of Chemistry, Chemistry World
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Articles

An Atomically Dispersed Copper-Catalyst Lights the Way to Selective N -Demethylations

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By Wenhao Su, Suman Prakash Pradhan, Jun Hu, Peng Ren, Nils Rockstroh, Alina A. Skorynina, Piotr Kustrowski, Susanna Monti, Giovanni Barcaro, Chaoqin Zeng, Jabor Rabeah, Aleksander Jaworski, Laura Simonelli, Adam Slabon, Shoubhik Das
| Nature Verified
Abstract N-demethylation is a key transformation in drug metabolism, medicinal chemistry, and late-stage amine diversification. Herein, we report a noble-metal-free, recyclable heterogeneous photocatalyst comprising atomically dispersed Cu sites on functionalized graphitic carbon nitride (Cu@f-gC3N4) for selective N-demethylation and N-dealkylation.
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Photocatalyzed oxidative cleavage of alkenes using CO 2 as an oxygen donor

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By Takuji Usui, Andrew Newman, Akshaye A. Bhambore, Yuman Qin, Peng Ren, Jun Hu, Suman K. Pradhan, Thanh Huyen Vuong, Xiufang He, Nils Rockstroh, Susanna Monti, Giovanni Barcaro, Aleksander Jaworski, Piotr Kustrowski, Jabor Rabeah, Sergey Bagnich, Anna Kohler Verified, Josef Breu, Gianvito Vilé, Matthias Beller, Shoubhik Das, Lulu Alluhaibi, Daniel Hohenberger
| Science Magazine Verified
Editor’s summary Structured Abstract Abstract Supplementary Materials References and Notes Information & Authors Metrics & Citations Check Access References Figures Tables Media Share Editor’s summary Slicing through carbon-carbon double bonds is a job for strong oxidants. Typical reagents include ozone and high-valent metal oxides. Carbon dioxide is essentially the thermodynamic opposite of those oxidants and conventionally reacts at the carbon rather than either oxygen. Remarkably, Qin et al.
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Electronic Transport in Porous Nanocrystals Enables Ultrasensitive Consistent Detection of Sulfur Dioxide under Variable Humidity Click to copy article link Article link copied!

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By Elissa O. Shehayeb, Joseph Chan, Giovanni Barcaro
| ACS Publications
2.1. MOF Synthesis and Characterization We synthesized DC-103 from a novel octahydroxy-functionalized TPz linker with a central cobalt ion, CoTPz(OH) 8 , coordinated to copper bridging ions through bis(dioxolene) linkages by following a similar approach to our previous report, (55) as detailed in Figures S1–S12 and Section S2 .
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