Guangying Tan
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Persistent acyclic Cp*Ir(III) complexes and their reactivities in cross-coupling reactions - Nature Communications
Abstract Iridium(III) complexes play a prominent role in organometallic chemistry, with significant research efforts directed toward Cp*Ir(III) species, broadly categorized into cyclic and acyclic types. Although studies on these two classes began roughly simultaneously, the development of acyclic Cp*Ir(III) complexes has lagged significantly behind their cyclic counterparts.
Construction of acenaphthylenes via C−H activation-based tandem penta- and hexaannulation reactions - Nature Communications
Abstract Acenaphthylene-containing polycyclic aromatic hydrocarbons (AN-PAHs) are noteworthy structural motifs for organic functional materials due to their non-alternant electronic structure, which increases electron affinity. However, the synthesis of AN-PAHs has traditionally required multiple sequential synthetic steps, limiting structural diversity. Herein, we present a tandem C−H penta- and hexaannulation reaction of aryl alkyl ketone with acetylenedicarboxylate.
Iron-Catalyzed para-Selective C-H Allylation of Aniline Derivatives
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