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Gufeng Yin

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Catalytic endo -stereoselective [2+2] cycloaddition of norbornadienes with internal alkynes

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By Longji Dai, Zekun Tuo, Xinye Xia, shuangshuang Li, Yunfei Lai, Chao Wang, Chong Qin, Xinyao Li, Wang Zhou, Gufeng Yin, Zhichao Chang, Zhongjin Zuo, Yongchun Hu, Shugen Kuang, Tzumei Wang
| Nature Verified
Abstract Facial stereoselective transformations of bicyclic compounds offer streamlined access to conformationally constrained scaffolds that are valuable in catalysis, materials science and drug discovery. Owing to the higher electron density of the highest occupied molecular orbital on the exo-face, norbornadiene (NBD), a typical bicyclic molecule, undergoes most reactions on its more accessible exo-face, whereas reactions on the endo-face remain underdeveloped.
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