Guo-Ying Han

Conflicts of Interest The authors declare no conflicts of interest. Data Availability Statement [CCDC 2434294 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.]. The data that support the findings of this study are available from the corresponding author upon reasonable request.

1 Introduction Increasing catalytic performance is often achieved by increasing the density of catalytic sites and/or improving the intrinsic activity of each site.[1-8] Jaramillo and co-workers have highlighted these two strategies as fundamental principles for designing catalysts.[1] Metal-organic frameworks (MOFs) serve as a model platform for catalytic studies, owing to their well-defined structural characteristics and highly dispersed catalytic sites.[9-16] Based on these design...

Conflict of Interest The authors declare no conflict of interest. Supporting Information Filename Description adfm202505730-sup-0001-SuppMat.docx5.2 MB Supporting Information References 1a) , , , , Coord. Chem. Rev. 2025, 526, 216361; b) , , , , , , , Coord. Chem. Rev. 2024, 505, 215690; c) , , , , , Chem. Rev. 2020, 120, 13087; d) , , , Nat. Energy. 2024, 9, 121; e) , , , , , , , , , , Coord. Chem. Rev. 2020, 419, 213388. 2a) , , , , , , , J. Am. Chem. Soc. 2008, 130, 13850; b) , , , , ACS Cent. Sci.