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Electrochemical Performance of NiCo‐MOF‐Derived NiO@NiCo2O4 Nanocomposite Electrode Materials for Supercapacitors
In this study, we investigate the effect of varying tannic acid (TA) concentrations on the electrochemicalperformance of NiCo-MOF-derived nanocomposite electrode materials. The TA@NiO@NiCo2O4 nanocomposites were synthesized using a straightforward metal–organic framework (MOF) templating strategy, which involved a simple hydrothermal method followed by a two-step annealing process. Electrochemical characterization reveals that the resulting nanocomposites exhibit excellent cycling stability.
Electrochemical oxidative monofluoromethylation of N-acryl-2-aryl benzimidazoles: access to CFH2-containing benzimidazo[2,1-a]isoquinolin-6(5H)-one derivatives
An efficient monofluoromethylation of N-acryl-2-aryl benzimidazoles was developed through an electro-oxidative CFH -radical generation, followed by cascade cyclization fabricating a benzimidazo[2,1-a]isoquinolin-6(5H)-one scaffold. The protocol used the readily available CFH SO Na as the monofluoromethylation reagent, enabling the step economical synthesis of polycyclic benzimidazoles in moderate to high yields under metal- and oxidant-free conditions.
Efficiently luminescent heteroleptic neutral platinum(II) complexes based on N^O and N^P benzimidazole ligands
Efficiently luminescent heteroleptic neutral platinum(II) complexes based on N^O and N^P benzimidazole ligands A series of new luminescent cycloplatinated(II) complexes (5a-8a and 5b-8b) with formula Pt(bt)(N^O) and Pt(bt)(N^P) have been synthesized [bt = phenylbenzothiazole, N^O =(2-(1H-benzimidazole)-phenyl)diphenylphosphine oxide derivatives for 1a-4a and N^P = (2-(1H-benzimidazole)-phenyl)diphenylphosphine derivatives for 1b-4b].
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