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Guojuan Yin on Muck Rack

Guojuan Yin

As seen in: Royal Society of Chemistry
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NBS-mediated C(sp3)-H amidation of N,N-dimethylamides with N-acyloxyamides

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By Shuangqing Li, Materials Engineering, Xianru Xu, Guojuan Yin
| Royal Society of Chemistry Verified
NBS-mediated C(sp3)–H amidation of N,N-dimethylamides with N-acyloxyamides† Presented herein is the NBS-mediated amidation of the C(sp3)–H bond adjacent to the nitrogen atom of N,N-dimethylamide using N-acyloxyamide as the amide source, leading to a diverse array of methylenebisamides. The transformation features mild conditions, excellent functional group tolerance, and high efficiency. The practicality of the methodology was shown by gram-scale synthesis and efficient product derivatization.
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