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Hanying Sun on Muck Rack

Hanying Sun

As seen in: Royal Society of Chemistry
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Articles

Ring-opening silylation of N-arylindoles via endocyclic C−N bond cleavage triggered by silylboranes

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By Ye Tian, Benqiang Cui, Hanying Sun, Shaoyue Han
| Royal Society of Chemistry Verified
Ring-opening silylation of N-arylindoles via endocyclic C−N bond cleavage triggered by silylboranes The cleavage of heteroaromatic endocyclic carbon-heteroatom bonds to assemble C-Si bonds is scarce. Here, we demonstrate an unprecedented dearomatization silylation of N-arylindoles arising from reductive activation initiated by electron-rich silylboronic complexes to deliver silyl styrenes with perfect stereoselectivity. You have access to this article This article has not yet been cited.
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