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Hiroko Aruga Katori on Muck Rack

Hiroko Aruga Katori

As seen in: Physical Review B
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Impact of oxidation state on the valence-bond glass physics in the lithium-intercalated ${\mathrm{Mo}}_{3}{\mathrm{O}}_{8}$ cluster Mott insulators

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By Yuya Haraguchi, Daigo Ishikita, Hiroko Aruga Katori
| Physical Review B
We have successfully synthesized four Mo3O8-type cluster Mott insulators (CMIs) by intercalating lithium into nonmagnetic precursors to regulate the Mo3 cluster valence. The resulting materials are Li1+xRMo3O8 (R=Sc,Y,Lu) and LixZn2Mo3O8. Our magnetic susceptibility measurements revealed that these materials display characteristics akin to a valence-bond glass state and suggest the presence of short-range ordering when the Mo3 cluster valence approximates its ideal value.
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