Hongjuan Xi on Muck Rack

Hongjuan Xi

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Articles

Micropore blocked core-shell ZSM-22 designed via epitaxial growth with enhanced shape selectivity and high n-dodecane hydroisomerization performance

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By Pengyu Niu, Hongjuan Xi, Minggui Lin, Qiang Wang
| Royal Society of Chemistry
A series of core-shell ZSM-22 (Z@S) was synthesized via epitaxial growth. The characterization results of Z@S validated that the acid sites located on the external surface of core ZSM-22 were passivated by the epitaxial shell of highly siliceous ZSM-22 and the acid strength of ZSM-22 remained unchanged. As comparison, highly siliceous and boron containing ZSM-22 were also synthesized and characterized.
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High selectivity for n-dodecane hydroisomerization over highly siliceous ZSM-22 with low Pt loading

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By Qiang Wang, Pengyu Niu, Hongjuan Xi, Minggui Lin
| Royal Society of Chemistry
Highly siliceous ZSM-22 was synthesized under hydrothermal condition with ZSM-22 seeds. Characterizations by FT-IR and 1H and 29Si NMR confirm that due to the existence of defective sites in the siliceous ZSM-22, acidic silanol groups including vicinal silanol and silanol nests are detected. Acidic silanol groups are considered as the acid site of siliceous ZSM-22.
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