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Rhenium coordination-induced conformational modulation in nitrogen-doped nanographene
Rhenium coordination-induced conformational modulation in nitrogen-doped nanographene† The conformation of nanographene plays a pivotal role in determining its electronic, mechanical, and optical properties. Analyzing the conformation of nanographene is crucial because of its significant implications in various scientific and technological domains. In this work, we examined the changes in the structural conformation of nanographene upon coordination with a metal.
Steric and Electronic Influences on Cu-Cu Short Contacts in β-Thioketiminato Tricopper(I) Clusters
Steric and Electronic Influences on Cu-Cu Short Contacts in β-Thioketiminato Tricopper(I) Clusters A series of β-thioketiminate copper(I) complex trimers [LCuI]3 were synthesized by modifying the ligand framework with electron-withdrawing groups (F and Cl) or electron-donating groups (iPr and Me) at the N-aryl ring as well as with CF3 groups on the chelating backbone.
K2CO3-Mediated (3+3-1) Annulation of 1,3-Acetonedicarboxylates with 2-Fluoro-1-nitroarenes: Synthesis of Indoles
K2CO3-Mediated (3+3-1) Annulation of 1,3-Acetonedicarboxylates with 2-Fluoro-1-nitroarenes: Synthesis of Indoles The K2CO3-mediated one-pot reaction of 1,3-acetonedicarboxylates with 2 equiv. of substituted 2-fluoro-1-nitrobenzenes has been developed to synthesize various 2,3-dicarboxylate indoles via a tandem (3 + 3 − 1) annulation pathway.
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