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Highly Efficient Hydrogenolysis of β-O-4 Bonds in Lignin Over Ru-Based Polyoxometalates Under Mild Conditions
1 Introduction The depletion of global fossil energy resources has made the development of green and sustainable alternatives an urgent priority [1, 2]. Lignocellulose has drawn significant interest among various sustainable options due to its wide availability, abundance, and renewability as a carbon source [3, 4]. Lignocellulose is composed of lignin, cellulose, and hemicellulose [5].
Boosting the Hydroformylation Activity of Polyoxometalate-Anchored Rh Single Atom Catalysts in Toluene-Water Media
Boosting the Hydroformylation Activity of Polyoxometalate-Anchored Rh Single Atom Catalysts in Toluene-Water Media In this work, the water-soluble single atom Rh substituted polyoxometalates (POMs) catalysts were constructed. The further 31P NMR, FT-IR, ICP-analysis, ESI-MS and HAADF-STEM characterization showed that Keggin-type or Dawson-type Rh-substituted POMs were constructed by a reaction of mono-lacunary POMs with RhCl3.
Multivacant polyoxometalate-stabilizing palladium nanoparticles catalyzes N‑formylation of amines with CO2 and H2
Multivacant polyoxometalate-stabilizing palladium nanoparticles catalyzes N‑formylation of amines with CO2 and H2 In this work, the Keggin-type tri- and mono-palladium substituted silicotungstates (POM) have been constructed by the reaction of the tri- and monovacant silicotungstate ([SiW9O34]10− or [SiW11O39]8−) with palladium chloride. The as-obtained potassium salts of POM demonstrate that the Pd2+ ions are incorporated into POM frameworks.
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