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Ida Rygaard Kocemba on Muck Rack

Ida Rygaard Kocemba

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Divergent concerted and stepwise cycloadditions via enantioselective cross-conjugated iminium-ion catalysis

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By Erlaitz Basabe Obregón, Chi Zhang, Mikk Kaasik, Philipp Waser, Pan-Pan Chen, K. N. Houk, Karl Anker Jørgensen, Ida Rygaard Kocemba, Metin Cakiroglu
| Nature Verified
Abstract Cycloadditions are described as either concerted or stepwise processes, where a catalyst can influence both the mechanism and the peri-, regio- and stereoselectivity. We report experimental and DFT-computational investigations that reveal the versatile reactivities of cross-conjugated unsaturated iminium-ion intermediates.
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