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Incoronata Tritto

As seen in: ACS Publications, Royal Society of Chemistry
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Articles

(Trialkylsilyl-cyclopentadienyl)titanium(IV) Dichloride Complexes Containing Ketimide Ligands, Cp’TiCl2(N=CtBu2) (Cp’ = Me3SiC5H4, Et3SiC5H4), as Efficient Catalysts for Ethylene Copolymerisations with Norbornene, Tetracyclododecene

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By Taiga Fujioka, Simona Losio, Incoronata Tritto, Minaho Kawatsu
| Royal Society of Chemistry Verified
(Trialkylsilyl-cyclopentadienyl)titanium(IV) Dichloride Complexes Containing Ketimide Ligands, Cp’TiCl2(N=CtBu2) (Cp’ = Me3SiC5H4, Et3SiC5H4), as Efficient Catalysts for Ethylene Copolymerisations with Norbornene, Tetracyclododecene Trialkylsilyl-substitued half sandwich titanium complexes containing ketimide ligands, (RC5H4)TiCl2(N=CtBu2) (R = SiMe3, SiEt3), especially the SiEt3 analogue, exhibited superior catalytic activities with efficient norbornene (NBE) incorporation (25700-91400...
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Synthesis of Sulfur-rich Polymers: Copolymerization of Cyclohexene Sulfide and Carbon Disulfide Using Chromium Complexes

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By Laura Boggioni, Selena Silvano, Chiara Francesca Carrozza, Incoronata Tritto
| ACS Publications
An investigation of the copolymerization of cyclohexene sulfide and carbon disulfide using salphen and salen Cr complexes as catalysts and [PPN]+X– salts as cocatalysts, at different temperatures and reaction times, is reported. Both catalytic systems produce both polymer and cyclic products. For the first time, poly(trithiocyclohexylcarbonates) (PCS) have been synthetized in high yields and high molecular weights.
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