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Overlooked impact of surface hydroxylation on the solubility of less-soluble compounds: a case study of CeO2

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By Tatiana Plakhova, Anna Yu. Romanchuk, Anastasia D. Konyukhova, Irina Seregina
| Royal Society of Chemistry Verified
Overlooked impact of surface hydroxylation on the solubility of less-soluble compounds: a case study of CeO2† Unexpectedly, the solubility of CeO2 nanoparticles (NPs) at 25 °C does not depend on particle size, but is significantly affected by the sample's thermal pre-treatment. The classical interpretation of NPs' solubility proposed by the Gibbs–Thompson or Kelvin equations fails to describe the experimental data on CeO2 solubility obtained in this study.
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