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Iu Cinquima on Muck Rack

Iu Cinquima

As seen in: Color Research & Application, Wiley Online Library, Royal Society of Chemistry, Chemistry World
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Articles

Shedding Light on the Precatalytic Mixture of Pd(OAc)2 and Cooperating Bipyridone Ligands for the C─H Functionalization of Arenes

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By Francisco José Villalba, Iu Cinquima, Ana C. Albéniz, Sara Martín-Martín
| Wiley Online Library Verified
1 Introduction The use of a precatalytic mixture of a commercially available metal salt and a suitable ligand is common practice in organometallic catalysis. It is convenient and easy from the operational point of view. The way this precatalytic mixture evolves to the actual active species is often an obscure issue. However, these off-cycle processes are important to determine the nature and concentration of the active species in the catalytic cycle.
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Columnar liquid crystalline triphenylene-bis(dithiolene)nickel complexes. Soft photothermal materials

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By Silvia Cobos, Iu Cinquima, Facultad de Ciencias
| Royal Society of Chemistry Verified
Columnar liquid crystalline triphenylene-bis(dithiolene)nickel complexes. Soft photothermal materials† This work reports new soft photothermal materials based on liquid crystalline nickel bis(dithiolene) complexes bearing pentakis(dodecyloxy)triphenylene units in which the triphenylene core and the metal complex are linked through –(CH2)n– (n = 2, 4, 10) connectors. The mesomorphic properties of these materials can be modulated by the length of the linker.
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Assessing the Cooperating Ability of 6‐Hydroxypicolinic Acid and Pyridyl‐Amide Ligands in Palladium‐Mediated C−H Activation

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By Cintya Pinilla, Iu Cinquima, Ana C. Albéniz
| Wiley Online Library Verified
Introduction Metal-ligand cooperation has been used in the last years as a strategy to facilitate the cleavage of crucial bonds in catalytic transformations, including the activation of the robust C−H bonds in the functionalization of hydrocarbons catalyzed by palladium complexes.1 The latter processes have proved to be an attractive, more convenient and sustainable alternative to the conventional Pd-catalyzed cross coupling reactions, which generally use organic halides and main-group...
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