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A Free-Radical Design Featuring an Intramolecular Migration for a Synthetically Versatile Alkyl-(Hetero)Arylation of Simple Olefins
A Free-Radical Design Featuring an Intramolecular Migration for a Synthetically Versatile Alkyl–(Hetero)Arylation of Simple Olefins A free-radical approach has enabled the development of a synthetically versatile alkyl–(hetero)arylation of olefins. Alkyl and (hetero)aryl groups were added concurrently to a full suite of mono- to tetrasubstituted simple alkenes (i.e., without requiring directing or electronically activating groups) for the first time.
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