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Stabilization of Alkanol–Alkanone Heteroclusters in Medium-Pore Zeolites Drives Orders-of-Magnitude Rate Enhancements in Proton-Catalyzed Dehydration Reactions
1 Introduction Solvents and additives, present as vapor-phase components or in liquid/dissolved forms, can alter mechanistic pathways and energy landscapes of reactions on a given catalytic surface over a wide range of coverage regimes (or extent of pore filling), providing extra degrees of freedom beyond catalyst engineering to achieve desirable activity and selectivity [1-5].
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