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Jirapa Suthala

As seen in: ACS Publications, Royal Society of Chemistry
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Articles

Efficient Ring Closing Metathesis by NHC-Supported (Arylimido)vanadium(V)-Alkylidene Catalysts Containing Perhalophenoxide Ligands: Exclusive RCM under High Substrate Concentration

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By Jirapa Suthala, Michael R. Buchmeiser, Kotohiro Nomura, Moe Unoki
| ACS Publications
Olefin metathesis has established itself as an important method for the synthesis of fine chemicals as well as advanced polymeric materials; (1−15) transition metal alkylidene (carbene) species play an essential role as catalysts.
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Efficient Ring Closing Metathesis by NHC-Supported (Arylimido)vanadium(V)-Alkylidene Catalysts Containing Perhalophenoxide Ligands: Exclusive RCM under High Substrate Concentration

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By Jirapa Suthala, Moe Unoki, Michael R. Buchmeiser, Kotohiro Nomura
| dx.doi.org
Olefin metathesis has established itself as an important method for the synthesis of fine chemicals as well as advanced polymeric materials; (1−15) transition metal alkylidene (carbene) species play an essential role as catalysts.
Open in Who Shared Issue with article?

Vanadium(V) Arylimido Alkylidene N-Heterocyclic Carbene Complexes Containing Fluorinated Alkoxide or Halogenated Phenoxide Ligands for the Syndiospecific ROMP of Cyclic Olefins

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By Kotohiro Nomura, Shuko Kuwahara, Jirapa Suthala, Yuta Kawamoto
| Royal Society of Chemistry Verified
Vanadium(V) Arylimido Alkylidene N-Heterocyclic Carbene Complexes Containing Fluorinated Alkoxide or Halogenated Phenoxide Ligands for the Syndiospecific ROMP of Cyclic Olefins [V(N-2,6-Cl2C6H3)(CHSiMe3)(OC6X5)(NHC)] [X = F (1), Cl (2), NHC = 1,3-bis-(2,6-dimethylphenyl)-imidazol-2-ylidene], exhibited remarkable catalytic activities [TOF = 133-193 sec-1 (1), 90.9-126 sec-1 (2)] for ring opening metathesis polymerisation (ROMP) of norbornene (NBE) at 25 ºC to afford ring-opened polymers not...
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