Jung-Ying Lin

First-row transition metal catalysts have gained prominence as sustainable and complementary alternatives to precious metal catalysts. (1−3) While they possess unique reactivity, often enabling single electron chemistry, this same advantage can become a limitation in screening and optimization.

Organometallics Cite this: Organometallics 2025, XXXX, XXX Click to copy citationCitation copied! . This publication is licensed under CC-BY 4.0 . You are free to share (copy and redistribute) this article in any medium or format and to adapt (remix, transform, and build upon) the material for any purpose, even commercially within the parameters below: Creative Commons (CC): This is a Creative Commons license. Attribution (BY): Credit must be given to the creator.

Introduction Click to copy section linkSection link copied! The merger of photoredox catalysis with transition metal catalysis, metallaphotoredox catalysis, provides a valuable approach for the formation of C–C bonds. (1) These transformations enable the cross-coupling of a diverse array of carbon electrophiles and carbon nucleophile equivalents by relying on a synergy between catalysts.