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Air-stable Pd(0) catalyst bearing dual phosphine ligands: a detailed evaluation of air stability and catalytic property in cross-coupling reactions
Air-stable Pd(0) catalyst bearing dual phosphine ligands: a detailed evaluation of air stability and catalytic property in cross-coupling reactions† We have synthesised an air-stable Pd(0) catalyst bearing donor and acceptor phosphine ligands (Complex 1). This study revealed the long-term air stability and catalytic property of Complex 1 as a catalyst for cross-coupling reactions, where it was stable in air for eight months.
Synthesis of an Air-Stable Pd(0) Catalyst Bearing Donor and Acceptor Phosphine Ligands
Download Hi-Res ImageDownload to MS-PowerPointCite This:Organometallics 2020, 39, 2 Ryota Sato Ryota Sato Tsukuba Research Center for Energy Materials Science (TREMS), Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan Takaki Kanbara* Takaki Kanbara Tsukuba Research Center for Energy Materials Science (TREMS), Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan...
Facile Synthesis of Thienopyrroledione-Based π-Conjugated Polymers via Direct Arylation Polycondensation under Aerobic Conditions
An exploration of the tolerance of a Pd-catalyzed direct arylation polycondensation under aerobic conditions was carried out. The polycondensation of 5-(2-ethylhexyl)thieno-[3,4-c]-pyrrole-4,6-dione with 2,7-dibromo-9,9-dioctylfluorene was accomplished smoothly in air by refluxing the solvents, without the need for additional catalysts or additives.
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