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Kanikarapu Suresh on Muck Rack

Kanikarapu Suresh

As seen in: Royal Society of Chemistry
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Gold(I)-Catalysed Cyclisation of (E)-Ketene-N,O-Acetals: A Synthetic Route to Spiro-Oxazole-γ-Lactones

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By Manoj Sethi, Akhila Kumar Sahoo, Kanikarapu Suresh, Prasad Rangu
| Royal Society of Chemistry Verified
Gold(I)-Catalysed Cyclisation of (E)-Ketene-N,O-Acetals: A Synthetic Route to Spiro-Oxazole-γ-Lactones In this study, we developed a cascade 5,5-cyclisation of internal ketene-N,O-acetals utilizing homogeneous Au(I) catalysis. This process involves an initial 5-exo-dig carbocyclisation, followed by a 5-exo-dig heterocyclisation that stereoselectively incorporates O-atom of water molecule into N-tethered propargyl alkyne.
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