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Catalytic Oxidation of Solid Carbon and Carbon Monoxide over Cerium-Zirconium Mixed Oxides
A series of cerium-zirconium mixed oxides was prepared and evaluated in the catalytic oxidation of solid coke with 10 vol.% O in He at 673 K using a thermogravimetric analyzer. The measured first order rate constant for coke oxidation was proportional to the catalyst loading when the mass ratio of catalyst to coke was low, which enabled the calculation of a surface area specific reaction rate.
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