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Keshab Kumar Adhikary on Muck Rack

Keshab Kumar Adhikary

As seen in: Royal Society of Chemistry
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Theoretical investigation of nucleophilic substitution reaction of phenyl carbonyl isothiocyanates with pyridines in gas and polar aprotic solvent

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By Francis Verpoort, Ordered Materials, Keshab Kumar Adhikary
| Royal Society of Chemistry Verified
Theoretical investigation of nucleophilic substitution reaction of phenyl carbonyl isothiocyanates with pyridines in gas and polar aprotic solvent† This study focuses on the mutual interaction of substituents in the nucleophile and substrate – cross interaction constant, ρXY, in the uncatalyzed aminolysis by substituting pyridine with phenyl carbonyl isothiocyanate. The mechanism was found to be a stepwise process with a rate-limiting breakdown of the –NCS leaving group.
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