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1 Introduction Nuclear magnetic resonance (NMR) spectroscopy has proven to be a powerful tool for investigating protein dynamics, yet motions occurring faster than the NMR timescale remain challenging to characterize [1-3]. In addition to relaxation-dispersion analyses [4, 5] and advanced pulse-sequence methodologies [6-8], lowering the temperature represents an attractive means of analyzing rapid dynamics by slowing them down enough to be observable [9-24].
Competition between N and O: use of diazine N-oxides as a test case for the Marcus theory rationale for ambident reactivity† Kevin J. Sheehy, a Lorraine M. Bateman, abd Niko T. Flosbach,c Martin Breugst *c and Peter A.
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