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Rotational Motion of Ligand-Cysteine on CdSe Magic-Sized Clusters

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By Takuya Kurihara, Akihiro Matano, Yasuto Noda, Kiyonori Takegoshi
| American Chemical Society
Structure and dynamics of organic ligand capping on the surface of clusters significantly influence the property and function of the clusters. Recently, we revealed that, in cysteine-capped (CdSe)34 magic-sized cluster (CdSe-Cys), ligand-cysteine has two capping structures, namely, monodentate ligand-cysteine with sulfur–cadmium bond and bidentate one with sulfur– and nitrogen–cadmium bonds.
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