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Kung‐Pern Wang on Muck Rack

Kung‐Pern Wang

As seen in: Color Research & Application
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Articles

One‐Step Synthesis of 2,5‐Diaminoimidazoles and Total Synthesis of Methylglyoxal‐Derived Imidazolium Crosslink (MODIC)

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By David Spiegel Verified, Venkata R. Sabbasani, Kung‐Pern Wang, Matthew D. Streeter
| Color Research & Application Verified
Abstract Here we describe a general method for the synthesis of 2,5‐diaminoimidazoles, which involves a thermal reaction between α‐aminoketones and substituted guanylhydrazines without the need for additives. As one of the few known ways to access the 2,5‐diaminoimidazole motif, our method greatly expands the number of reported diaminoimidazoles and further supports our previous observations that these compounds spontaneously adopt the non‐aromatic 4(H) tautomer.
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