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Lara Cancela on Muck Rack

Lara Cancela

As seen in: ACS Publications
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Articles

Azolium Control of the Osmium-Promoted Aromatic C-H Bond Activation in 1,3-Disubstituted Substrates

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By Lara Cancela, Miguel A. Esteruelas, Montserrat Oliván, Enrique Oñate
| ACS Publications
Introduction The transition-metal-promoted activation of aromatic C–H bonds is one of the most relevant reactions in current chemistry, (1) due to the wide range of fields with which it is connected, ranging from organic (2) and organometallic (3) synthesis to catalysis (4) and materials science. (5) The reaction is initiated by the coordination of the C–H bond to the unsaturated metal center of the promoter.
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Electronic Communication in Binuclear Osmium- and Iridium-Polyhydrides

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By Miguel A. Esteruelas, Montserrat Oliván, Lara Cancela, Javier Galbán
| ACS Publications
Reactions of polyhydrides OsH6(PiPr3)2 (1) and IrH5(PiPr3)2 (2) with rollover cyclometalated hydride complexes have been investigated in order to explore the influence of a metal center on the MHn unit of the other in mixed valence binuclear polyhydrides. Hexahydride 1 activates an ortho-CH bond of the heterocyclic moiety of the trihydride metal–ligand compounds OsH3{κ2-C,N-[C5RH2N-py]}(PiPr3)2 (R = H (3), Me (4), Ph (5)).
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